南海北部西沙海槽沉积物管状黄铁矿特征及其形成机理*

南海北部西沙海槽S1站位的岩心柱沉积物中广泛发育自生矿物黄铁矿,其形态以管状为主,且具有内部中空的圈层结构。使用扫描电镜、电子探针、LA-ICP-MS、SIMS等测试方法研究了管状黄铁矿的形态及圈层结构,结果显示: (1)管状黄铁矿发育内部中空的圈层结构,其中内圈层(I_py)由莓球状黄铁矿呈五角十二面体紧密堆积组成,外圈层(O_py)由晶形较好晶粒较大的八面体黄铁矿组成,并混有沉积碎屑及钙质生物壳体;(2)内圈层和外圈层分别呈现出贫S富Fe和富S贫Fe的特征,其成因是甲烷渗漏造成的局部还原环境使得As进入黄铁矿中导致晶格空缺或被扭曲,从而促进Ni、Co、Cu、Zn、Pb等微量元素的掺入;(3)内圈层、外圈层发生了明显的硫同位素分馏现象,内圈层中 δ³⁴S 平均为-37.8‰,外圈层中 δ³⁴S 平均为-29.3‰。研究认为,管状黄铁矿作为曾经甲烷渗漏的通道,其生长机制可分为3个阶段: (1)气水通道形成阶段: 向上运移的甲烷流体在沉积物孔隙中逐渐形成气水通道;(2)外圈层形成阶段: 当向上运移的甲烷与硫酸盐发生甲烷厌氧氧化时,逐渐形成晶体较大、晶形较好的八面体黄铁矿外圈层;(3)内圈层形成阶段: 随着甲烷浓度逐渐降低,在气水通道中的微生物作用下,剩余甲烷与向下运移的硫酸盐继续反应形成莓球状黄铁矿内圈层。因此,南海北部的泥岩中大量发育的管状黄铁矿常常与地层中甲烷水合物的存在有关。     

Genesis of S-type Granites in the Pengshan Sn-polymetallic Ore Field, Northern Jiangxi Province and its Implications

The Pengshan Sn-polymetallic ore field is located in the southeastern part of the Yangtze block, spanning the southeast edge of the MLYDZ and the northern edge of the mid-segment of the Jiangnan Uplift, and on one side of the MLYDZ. The studies of LA–ICP–MS zircon U–Pb chronology and petrogeochemistry for Early Cretaceous acid granites from the Pengshan ore field were carried out in this paper. We report zircon U–Pb geochronology and whole-rock geochemistry for acid granites in the Pengshan ore field. The zircon U–Pb ages of the muscovite-granite, biotite adamellite and granite-porphyry are 127.6 ± 1.7 Ma, 126.9 ± 1.6 Ma and 126.6 ± 2.0 Ma, respectively. The granites in Pengshan are characterized by a high silicon content and are rich in alkali. They belong to high-potassium, calc-alkaline, peraluminous granite. The rocks have a relatively high Rb/Ba ratio, and the data points for muscovite-granite and biotite adamellite all fall within the clay-rich sources region, near the pelite-derived end-member, showing that the Pengshan muscovite-granite and biotite adamellite mainly originated from the partial melting of metapelites with high maturity. The transformation of the compressional and extensional tectonics in this region approximately 128 Ma obviously lags behind that in the mid-segment of the Jiangnan Uplift (135 Ma), but occurred earlier than the MLYDZ (126 Ma). The Pengshan ore field extends from the mid-segment of the Jiangnan Uplift to the MLYDZ. Although the tectonic stress field is constrained by the combination of the two secondary tectonic units, the time of tectonic system transformation is closer to the MLYDZ because the spatial orientation of the area is enclosed in the MLYDZ. Relevant geophysical and drilling data confirm the rationality of Pengshan–Ao’xia as a multi-center vertical zoning ore field, and show the scientificity of the prospecting idea of abutting joint between the north-west of Pengshan area and the south-east of Ao’xia area.     

基于波形特征的露天钼矿微震事件的识别分析——以卓资山钼矿为例

基于前人研究成果以及现场的实测结果，采用卓资山露天钼矿微震监测项目产出资料，提取了5类微震事件的波形特征和时频特征。波形特征显示:微地震的振幅、辐射均匀性和频率变化特征表明微地震是由于岩层受到单力偶和剪切力作用破裂而产生；爆破具有P波初动方向向上、S波不易识别的特点，包含“初震段、主震段、尾波段”三段变化形态；小型边坡滑坡波事件属楔体滑坡，是由多个“加速—缓冲—终止”构成，波形是由包络线呈“V”字形的多组脉冲波列组成；机械开采震动事件具有自振能量不变、脉冲幅度相差很大、持续时间间隔不确定的特点；运输车辆波形振幅具有形态“弱—强—弱”、等频率、包络线呈多段纺锤形的特征。时频空间分布可以分为相对独立、界限分明的两类:一类包含微地震、爆破、机械开采、小型边坡滑坡事件，另一类只包含车辆运输事件。     

A brief review of ENSO theories and prediction

Although the El Ni?o-Southern Oscillation(ENSO) originates and develops in the equatorial Pacific, it has substantial climatic impacts around the globe. Thus, the ability to effectively simulate and predict ENSO one or more seasons in advance is of great societal importance, but this remains a challenging task. The main obstacles are the diversity, complexity,irregularity, and asymmetry of ENSO. The purpose of this article is to organically integrate the understanding of ENSO based on current progress on the physical mechanisms, prediction, and connections between the interannual ENSO phenomenon and physical processes on other time and space scales, and to provide guidance for future studies by extracting specific important questions.     

Variation in the vertical zonality of erodibility and critical shear stress of rill erosion in China's Hengduan Mountains

Soil erodibility is an essential parameter used in soil erosion prediction. This study selected the Liangshan town watershed to quantify variation in the vertical zonality of rill erodibility (k_r) in China's ecologically fragile Hengduan Mountains. Soil types comprised of yellow–brown (soil A), purple (soil B), and dry-red (soil C) in a descending order of occurrence from the summit to the valley, which roughly corresponds to the vertical climate zone (i.e. cool-high mountain, warm-low mountain, and dry-hot valley sections) of the study area. With elevation, vertical soil zonality varied in both soil organic matter (SOM) content and soil particle-size fractions. A series of rill erosion-based scour experiments were conducted, using water discharge rates of 100, 200, 300, 400, 500, and 600 mL min^-1. Additionally, detachment rates (Dr) were measured under three hydrological conditions (the drainage, saturation, and seepage treatments). Results show that both Dr and flow shear stress (Ʈ) values increased as discharge increased. As elevation increased, the k_r values decreased, while the vertical zonality of critical shear stress (Ʈ_c) values showed no obvious variation. The highest k_r values were observed during the seepage treatment, followed by the saturation treatment then drainage treatment, indicating that variation in vertical hydraulic gradients could significantly alter k_r values. This study also found that land-use types could also alter k_r and Ʈ_c values. Further research, however, is necessary to better quantify the effects of subsurface hydrological conditions and land-use types on k_r under different soil zonalities in China's Hengduan Mountains. © 2018 John Wiley & Sons, Ltd.     

Comparisons of Salinity Adaptation in Terms of Growth,Body Composition,and Energy Budget in Juveniles of Rainbow and Steelhead Trouts (Oncorhynchus mykiss)

This study examined the effect of different salinities(0, 5, 10, 15, 20, 25 and 30) on the growth performance and energy budget of juveniles of two different ecotypes of Oncorhynchus mykiss, landlocked rainbow trout and anadromous steelhead trout. In the 42 d experiment, fish were cultured in three replicate tanks per salinity treatment(eight fish per tank). At the end of the experiment, the growth of rainbow and steelhead trouts was significantly higher at salinities of 5 and 10, respectively, than at all other salinities. The protein, lipid and energy content of both ecotypes declined with the increase of salinity. Based on their energy budgets, the percentage of energy consumed for growth by rainbow and steelhead trouts were significantly higher at salinities of 5(34.00% ±1.69%) and 10(43.76% ± 1.29%), respectively, than at all other salinities. The percentage of energy consumed for respiration by rainbow and steelhead trouts was lower at salinities of 5(54.90% ± 1.77%) and 10(46.73% ± 0.62%), respectively, than at all other salinities. Our results indicated that the salinity adaptation ability of juvenile steelhead trout was slightly better than that of juvenile rainbow trout, and salinities of 10 and 5, respectively, were most suitable for growth of these two fishes.     

江南造山带(湖南段)金矿成矿规律与资源潜力

扬子地块—华夏地块经历武陵期—雪峰期增生造山-碰撞造山形成江南造山带,构成统一的华南板块,进入板内演化阶段。本文从构造-岩浆作用-沉积建造角度,结合地质年代学、古地磁、岩相古地理分析,加里东运动、印支运动属陆内作用,造就了加里东期、印支期两次主要的金矿成矿事件。湖南雪峰山—幕阜山(俗称“金腰带”)加里东期和印支晚期金矿床分区成带产出,构成一条复合型造山型金矿带。区域性构造导矿、次级构造交汇或叠加控矿明显;矿石普遍发育条带状构造,属韧性剪切递进变形的产物。通过对区域成矿背景、金矿成矿理论,金矿床(体)地质特征,结合同位素地球化学、地质找矿成果及深部验证情况等多方面研究表明该成矿带深部找矿潜力巨大,2000 m以浅金远景资源量有望达到3000 t。     

四川甲基卡锂矿伟晶岩转石分布区“3定2参”大比例尺填图法及其在青藏高原应用的意义

我国西部地区无论是新疆阿尔泰还是地处青藏高原的西昆仑地区或是松潘-甘孜成矿带,都是我国伟晶岩型矿床找矿远景区,但要么剥蚀严重,要么第四系覆盖,难以找到好的地质露头。本文以地处青藏高原东南缘的川西甲基卡矿田为例,通过近10年来的实践,探索出一套在第四系覆盖严重但又有伟晶岩转石分布地区的填图找矿方法--"3定2参"1∶2000伟晶岩转石填图法,即:定伟晶岩转石类型、尺度、密度,参考矿区内伟晶岩脉产状和地形条件。实践证明,该方法能够快速有效识别伟晶岩转石类型(冰碛物、坡积物和原地或半原地型),并可进一步确定第四系覆盖区内伟晶岩脉的类型、产状及规模,为钻探工程部署提供依据。2019年在甲基卡经8个钻孔验证,在日西柯第四系覆盖区内发现16条花岗伟晶岩脉,其中锂辉石伟晶岩脉10条,实现了新的找矿突破。这一方法同样在可尔因矿集区适用,并指导2019年"松潘-甘孜成锂带锂铍多金属大型资源基地综合调查评价"项目在上述两个地区实施钻探验证,初步探获新增氧化锂资源量超过15万吨,值得进一步推广应用。     

GBW10010a大米标准物质复(研)制及数据特征

随着我国对生态文明建设的重视，自然资源综合调查势在必行，对生物标准物质亦提出了新的需求。当前相关调研工作已经大面积开展，自然资源综合调查、农产品与食品安全评价都需要对生物样品元素组成进行准确测试，需要以生物标准物质作为生物成分测试量值比对和溯源的基础，因此对生物基体标准物质的需求量大幅增加。大米作为主要粮食之一，其食品安全日益受到重视，对大米中的化学成分进行准确的分析测试具有重要的现实意义，因而对大米标准物质的需求量尤为突出，但目前大米成分分析标准物质已供不应求。本文严格按照《标准物质定值的通用原则及统计学原理》（JJF 1343—2012）和《地质分析标准物质的研制》（JJF 1646—2017）等相关规范要求，开展了GBW10010a大米成分分析标准物质的复（研）制工作，包括样品采集、加工制备、均匀性检验、稳定性检验、多家实验室协作定值测试及不确定度评定等关键环节。结果表明：本次复（研）制的大米标准物质定值成分多样、量值准确可靠，符合国家一级标准物质的要求。GBW10010a共定值54项主微量元素，包括Ag、Al、As、B、Ba、Be、Bi、Ca、Cd、Ce、Co、Cr、Cs、Cu、Dy、Er、Eu、Fe、Gd、Ge、Hg、Ho、K、La、Li、Ho、Mg、Mn、Mo、N、Na、Nb、Nd、Ni、P、Pb、Pr、Rb、S、Sb、Sc、Se、Si、Sm、Sr、Tb、Th、Tl、Tm、U、V、Y、Yb、Zn，其中的39项元素给出了标准值及不确定度，包括Ag、Al、As、B、Ba、Ca、Cd、Ce、Co、Cs、Cu、Dy、Er、Fe、Hg、K、Li、Mg、Mn、Mo、N、Na、Nd、Ni、P、Pb、Pr、Rb、S、Sb、Se、Si、Sm、Sr、Tb、Tl、Y、Yb、Zn；15项元素提供参考值，包括Be、Bi、Cr、Eu、Gd、Ge、Ho、Ho、La、Nb、Sc、Th、Tm、U、V。与原有GBW10010大米标准物质相比较，GBW10010a中As、Cd、Co、Cr、Cu、Hg、Mn、Mo、Ni、Zn等重金属元素含量显著下降，其中Cd、Cu、Zn降幅较大，分别下降约39%、43%、38.7%，一定程度上反映了农田生态环境的改善。本批标准物质定值元素总数量增加了6项，新增定值元素Ag、Nb（Nb给出参考值），并且各项元素不确定度范围整体上有所缩小，如Al、Cd、Cu、Fe、K、Mg、Mo、Na、P、Pb、Se、Zn等对生物易有影响的重要元素，表明了地质分析测试方法技术的进步及定值水平的提高。本批标准物质定值元素涵盖了具有生物效应的大部分主微量元素，适用于农业生态环境地球化学调查与评价、生物样品测试、农产品质量与食品安全评价样品测试时的分析仪器校正、分析方法评价和分析质量监控等多个领域。